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Material Safety Data Sheet (Msds) Of Polyvinyl Alcohol
PRODUCT IDENTIFICATION
CAS NO 9002-89-5
EINECS NO. 209-183-3
FORMULA [-C2H4O-]n

TOXICITY

Oral rat LD50: > 20 gm/kg
SYNONYMS PVOH; Ethenol, homopolymer; PVA; Polyviol; Vinol; Alvyl; Alkotex; Covol; Gelvatol; Lemol;
   
PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE white flake
MELTING POINT ca 200 C
BOILING POINT 228 C
SPECIFIC GRAVITY 1.19 - 1.31
SOLUBILITY IN WATER Moderately soluble
pH neutral or slightly acid
NFPA RATINGS Health: 0 Flammability: 2 Reactivity: 0
FLASH POINT

79 C

STABILITY Stable under ordinary conditions
   
First Aid Measures
Inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
Not expected to require first aid measures.
Skin Contact:
Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Wash thoroughly with running water. Get medical advice if irritation develops.

Fire Fighting Measures
Fire:
Flash point: 79C (174F) OC
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Minimum dust cloud ignition temperature: 450C (842F).
Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Maximum explosion pressure: 78 lb./sq. in.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

Preventive Measures
Accidental Release Measures
Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container.
Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Separate from incompatibilities. Avoid dust formation and control ignition sources. Employ grounding, venting and explosion relief provisions in accord with accepted engineering practices in any process capable of generating dust and/or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents into a non-inert atmosphere where flammable vapors may be present could cause a flash fire or explosion due to electrostatic discharge.

Protective Measures
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles.

Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Complete combustion will emit carbon dioxide and water when heated to decomposition. Incomplete combustion gives in addition carbon monoxide and oxidation products, including organic acids, aldehydes and alcohol.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers.
Conditions to Avoid:
Heat, flame, ignition sources, dusting and incompatibles.